Department of Chemistry, University of Alberta
November 1999
There are no fixed publishing dates for this newsletter; its appearance solely depends on whether there is a need to present information to the users of the spectrometers or not.
Other content of this NMR News is no longer meaningful and has been removed April 2010.
Contents
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FAQ
99-08.1 digital resolution, what is it? Two terms should be distinguished: (a) the spectral resolution which is the natural linewidth of a sample plus any line distortion due to imperfect shimming (b) the digital resolution which is dependent on the acquisition time which in turn is linked to the ratio of 2sw / np Without zero-filling (i.e. np = fn) the digital resolution is related to the acquisition time (as shown in equation below). Note, however, that while np can be any number, the Fourier Transform (FT) algorithm works only with fn values that are a multiples of 2 (..., 1024, 2056, 4096, 8192, 16384, 32768 etc. also called 1K, 2K, 4K, 8K 16K, 32K, 64K etc.). Poor digital resolution, especially a problem in
2D experiments, can lead to severe peak distortion as shown in the examples
below. All spectra show the same proton signal: on top at a very poor
digital resolution with the two
vertical lines showing two digitization points separated by 2.9 Hz, on the bottom at
high digital resolution (0.2 Hz/pt). It is obvious that
poor digitization
can lead to misinterpretations.
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number
of data points (np): 16K |
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number
of data points (np): 24K |
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number
of data points (np): 24K |
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